Liquid products of thermochemical processing of lignocellulosic biomass (biooil) are the dark liquid with smoky odor. When produced from lignocellulosic feedstock biooil conform the requirements of ASTM D 7544-10.
Table. Main properties of pyrolysis liquid products
№ | Parameter, Unit | Value |
1 | Lower heat of combustion, MJ/kg, more than | 15 |
2 | Density at 20°С, kg/m3 | 1100-1300 |
3 | Water content, w%, less than | 30 |
4 | Content of solid particles, w%, less than | 2,5 |
5 | Kinematic viscosity at 20°С, mm2/с, less than | 125 |
6 | Sulfur content, w%, less than | 0,05 |
7 | Ash content, w%, less than | 0,25 |
8 | Ignition point, °C, more than | 45 |
9 | Pour point, °C, less than | -9 |
10 | pH | 2-3 |
Liquid products of fast ablative pyrolysis of lignocellulosic feedstock contain low-molecular compounds and oligomeric products and resins.
Solid products of thermochemical processing of lignocellulosic biomass represent fine-dispersed black powder with high carbon content.
Table. Main properties of char
№ | Parameter, Unit | Value |
1. | Lower heat of combustion, MJ/kg | 20-33 |
2. | Density, kg/m3 | 260-380 |
3. | Carbon content, w% | 40-70 |
4. | Ash content, w% | До 15 |
5. | Characteristic size, mm | 0,1 |
Biooil application:
- Alternative fuel for small and public energy production (application in boilers as replacement for petroleum derived heating oil and fuel oil.
- Components of motor fuels
- Binder for composite materials (production of biopolymers, replacement of phenol in phenol- formaldehyde resins, replacement of polyols in polyurethanes up to 30%):
- Feedstock for road construction (addition to bitumen as adhesive up to 30%);
- Feedstock for chemical industry (separation of useful components, rectification, production of oils and motor fuels).
Engine operation on liquid pyrolysis products